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"Fertilizer & Sulfate Attack"
Time-Tested Performance
Sulphates in solution attack concrete and cause
expansion, deterioration, and eventual disintegration. In the
early stages of attack there is little visual evidence of any
change in the concrete, although there may be some reduction in
strength as the chemical action proceeds. This is accompanied
by slight expansion, which may not be apparent in the concrete
itself, but may cause trouble at points of restraint. As the attack
proceeds there is usually some change in color from the normal
cement grey, and cracking or spalling occurs, starting from the
surface in dense concrete, but penetrating much deeper in more
porous concrete.
Fertilizers often contain ammonium, potassium
and magnesium sulphates. Generally, inorganic acids are destructive
to concrete. These may also be released from some salts such as
ammonium chloride and ammonium nitrate by interaction with lime.
Leaching then follows. A number of fertilizers are soluble in
water, enabling the chemical easy pathway to the interior of the
concrete.
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Form in which the sulphate occurs.
Easily soluble sulphates such as those of sodium, potassium,
magnesium, and ammonium, react more vigorously than calcium
sulphate or gypsum.
-
Concentration.
The higher the concentration of sulphates in solution the more
serious the attack. The severity of attack is increased in circumstances
in which a flow of sulphate- bearing water brings a continuous
supply of the salt into contact with the concrete.
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PH value of the soil or groundwater.
Its temperature may also be a factor at ground level, the activity
of sulphate solutions increase with temperature. If the pH value
is below 6 in acid soils, the rate of attack is likely to be
increased.
-
Permeability of the concrete.
Permeable concrete, particularly if one side is in contact with
moist soil containing sulphates and the other side is open to
the air so that evaporation occurs, is attacked throughout its
thickness resulting in an overall expansion and complete disintegration.
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Formation of cracks.
Attack proceeds along the lines of cracks particularly when
the movement of moisture along any crack is encouraged by one-sided
water pressure of evaporation from a free surface.
-
Sulphates.
Sulphates of sodium potassium, magnesium and ammonium may cause
serious damage to Portland cement concrete in the presence of
moisture. This begins by expansion within the concrete, which
may be enough to cause general expansion in the member. Cracking
and disruption follow. Cracks provide a path for soluble chemicals
to migrate into the interior of the structure causing deterioration
of the concrete.
Sulphate salts attack concrete only when they
are in solution. It follows that attack is most severe when the
soil conditions allow a free movement of ground water.*
Because concrete is porous, and any foreign material
can penetrate into the concrete as water-soluble, the solution
is to stop the penetration of these chemicals by stopping the
capillary action. SEAL-IT Concrete Sealant provides a permanent
internal seal, which forms a hydrostatic head, barring the migration
of moisture. SEAL-IT Concrete Sealant provides a water barrier
so moisture as well as water soluble contaminants sit on the surface
instead of penetrating and destroying the concrete.
SEAL-IT Concrete Sealant also increases the strength
of the concrete at the surface. This will retard attacks of harmful
chemicals at the surface, protecting the vulnerable interior of
the concrete, thereby increasing the life- expectancy and safety
of the structure.
*ASTM-C-67-Section13.
Results: 25% decrease in absorption.
*Compression Strength (surface coat only). Results: +15% at 8
days;
+23% at 31 days.
**Concrete Materials and Practice Fifth Edition
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